phosphine

phosphine

1. In 1978, John H. Clark at Los Alamos Scientific Laboratories for the first time removed the common impurities of silane, such as phosphine (PH3) and arsine (AsH3), by irradiating the silane gas with a pulsed ultraviolet laser.

1978年,洛斯阿拉莫斯科学实验室的克拉克(John h. Clark)第一次通过用脉冲紫外激光照射硅烷气体的办法,除去硅烷中象磷化氢(Ph3)和砷化三氢(Ash3)这类普通杂质。

2. APO resin (tris-aziridinyl phosphine oxide resin)

apo树脂,三乙烯亚胺基膦化氧树脂

3. PNMR and X-ray diffractometric results revealed the fac-configuration of phosphine ligands.

PNMR和X-射线结构分析表明膦配体为面式构型。

4. tridecyl phosphine oxide(TDPO)

[化] 氧化三癸基氧膦

5. tri-2-ethylhexyl phosphine oxide(TEHPO)

[化] 氧化三膦; 氧化三-2-乙基己基膦

6. tridodecyl phosphine oxide(TDPO)

[化] 氧化三膦; 氧化三十二烷基膦

7. AN ALTERNATIVE TO THE FAO METHOD FOR DETERMINING HIGHER- LEVEL RESISTANCE INSECTS TO PHOSPHINE

一种替代FAO方法测定储粮害虫磷化氢高抗性的方法

8. Survey on an acute phosphine poisoning

一起急性磷化氢中毒事故调查

9. Survey on 3 cases of phosphine poisoning caused by insect- drive

一起熏虫引起3例磷化氢中毒的事故调查报告

10. An Investigation on a Case of Acute Phosphine Poisoning Caused by Ferrosilicon

一起硅铁致磷化氢急性中毒事故

11. Keywords 1-butene;Rhodium Phosphine Complex;hydroformylation;Kinetics;

丁烯;铑配合物;氢甲酰化;动力学;

12. Keywords Trialkyl Phosphine Oxide(TRPO);Radiolysis;FI IR Spectrometry.;

三烷基氧化膦(TRPO);辐照分解;傅里叶红外光谱法;

13. Keywords Trialkyl Phosphine Oxide;Gas Chromatographic;Extractant.;

三烷基氧膦;气相色谱;萃取剂;

14. Keywords Trialkyl Phosphine Oxide;Extractant;Gas Chromatography;Mass Spectroscopy.;

三烷基氧膦;萃取剂;气相色谱;质谱;

15. Reactive extraction equilibria behavior of monocarboxylic acids by trialkyl phosphine oxide

三烷基氧膦反应萃取一元羧酸的规律

16. The Study of GC on Chemical Constituents for Trialkyl Phosphine Oxide

三烷基氧膦成分的气相色谱研究

17. The trialkyl phosphine oxide (TRPO) has been used for extractant of radioactive waste and chemical separation process of organic acid.

三烷基氧膦(TRPO)用于做放射性废液和化学分离过程的萃取剂。

18. tris hydroxymethyl phosphine

三羟甲基膦

19. Keywords triphenyl phosphine;rhodium;mesostructured cellular foam;supported catalyst;propylene;hydroformylation;

三苯基膦;铑;介孔泡沫材料;负载型催化剂;丙烯;氢甲酰化;

20. Keywords Asymmetric hydrogenation;Chiral diphosphine;Rh phosphine complexes;Phenylalanine derivatives;

不对称氢化;手性双膦;铑膦配合物;苯丙氨酸衍生物;

21. Keywords Propene;Supported rhodium phosphine catalyst;Hydroformylation;Solution NMR;

丙烯;负载型铑膦催化剂;氢甲酰化;溶液NMR;

22. Keywords biphase catalysis;1 dodecene;hydroformylation;rhodium phosphine complex;micell;O/W emulsion;

两相催化;十二碳烯;氢甲酰化;铑膦配合物;胶束;O/W型乳状液;

23. Tri(2-thiophenyl)phosphine (P(C6H4-2-SH)3, PS3) was designed at 1989.

中文摘要三-2-硫酚膦基(P(C6H4-2-SH)3,PS3)这配位子在1989年即被化学家设计出来。

24. N,N-dimethyl-3-oxa-glutaramic acid(DOGA) was purified and characterized to analyze treatment of DOGA in a simplified trialkyl phosphine oxide(TRPO) process.

为提供三烷基氧膦(TRPO)简化流程中N,N-二甲基-3-氧杂-戊酰胺酸(DOGA)反萃液后续处理的依据,纯化并表征了DOGA,并对其热分解过程及非等温动力学进行了研究。

25. Keywords Diacetyl monoxime;Palladium chloride;Triphenyl phosphine;Tetramethylpyrazine;Kinetics;

二乙酰一肟;钯/三苯基膦;四甲基吡嗪;动力学;

26. bis[hydroxymethyl] phosphine acid

二羟基次膦酸

27. ferrocene chiral phosphine ligand

二茂铁手性膦配体

28. triphenyl phosphine methylene

亚甲基三苯膦

29. It is introduced that analyzing phosphine by GC method is a good method.

介绍了二氧化碳中的磷烷分析。

30. Recovery of 2 -Mercaptobenzothiazole and Triphenyl Phosphine Oxide from Dregs Generated in Cefotaxime Sodium Production

从头孢噻肟钠生产废渣中回收2-巯基苯并噻唑和三苯基氧膦

31. Determination of Trace Amounts of Chloride ion in Triphenyl Phosphine by Low-Pressure Ion Chromatography

低压离子色谱法测定三苯基膦中痕量氯离子

32. Rely on technological progress and advanced research and development advantages, as the successful development of high-performance, green biodegradable no phosphine water treatment products.

依靠技术进步和先进的研发优势,最新开发成功性能优良,绿色可生物降解无膦水处理产品。

33. Keywords tobacco warehouse;phosphine;the equipment of automatic fire alarm system;anti-corrosion;

关键词烟叶仓库;磷化氢;火灾自动报警系统设备;防腐;

34. Keywords Electrochemistry;Fe-onry hydrogenase;Iron surfide;Phosphine ligand;Ruthenium;

关键词电化学;唯铁氢化酶;铁硫配合物;膦配体;钌;

35. Keywords Cu(I) complex;tri(p-methoxyphenyl)phosphine;crystal structure.;

关键词铜(I)配合物;三(对甲氧基苯基)膦;晶体结构;

36. Effects of Cryo-Temperature and Excitation Voltage on Determination of Trace Phosphine by Gas Chromatography

冷阱温度和激活电压对气相色谱分析痕量磷化氢的影响

37. From the angles of the biology and reaction kinetics,this paper proves that the course of phosphorus compound's transformation into the gaseous phosphine is feasible.

分别从生物学角度和反应动力学角度证明了含磷化合物转化成气态磷化氢的过程是可行的。

38. About thirty bidentate neutral phosphine ox-ides including carbamoylmethylene phosphine ox-ides(CMPO)and tetraalkylalkylene diphosphineoxides(DPO)used as extractants are listed inthis paper.

列出了30余种双配位基中性氧化膦类萃取剂,其中包括甲氨酰甲撑氧膦(CMPO)和四烷基(或苯基)烷撑双氧膦(DPO)两类,并给出了它们自无机酸介质中萃取某些锕系元素的萃取率.

39. Determination of Phosphine Liberated in the Storage of Amorphous Red Phosphorus by Headspace Gas Chromatography

利用气相色谱顶空装置测定红磷储存过程中生成的磷化氢

40. dodecyl dimethyl phosphine oxide

十二烷基二甲基膦氧化物

41. Keywords anaerobic;matrix-bound phosphine;acidification;acidogenic bacteria;granular;

厌氧;结合态磷化氢;酸化;产酸菌;颗粒污泥;

42. However, shaking cultivation could promote the anaerobic phosphorus removal because of its helping phosphine release.

厌氧振荡培养可促进磷化氢的释放,从而提高磷酸盐去除率。

43. Keywords anaerobic phosphate removal;anaerobic phosphate reducer;poly-phosphate deoxidize;phosphine;

厌氧除磷;厌氧除磷菌;聚磷盐还原;磷化氢;

44. bis[hydroxymethyl] methyl phosphine oxide

双羟甲基甲基膦化氧

45. bis (4-methylphenyl) phenyl phosphine sulfide

双(4-甲苯基)苯基硫化膦

46. bis (4-carboxyphenyl) phenyl phosphine oxide

双(4-羧苯基)苯基氧化膦

47. Keywords N;N bis(diphenylphosphinomethyl)piperazine;amphiphilic phosphine;palladium complex;carbonylation;

双(二苯膦甲基)哌嗪;含氮两亲膦体;钯配合物;羰基化反应;

48. bis 4-carboxyphenyl phenyl phosphine oxide

双(对-羧苯基)苯基氧化膦

49. bis (4- carboxyphenyl) phenyl phosphine oxide ( BCPPO)

双(对羧苯基)苯基氧化膦

50. With it is impossible that dosage was compared directly 2001, because only 8 cities join investigation, and in these 8 cities the soybean field of 73 % uses careless pleasant phosphine.

同2001年用量直接比较是不可能的,因为仅有8个州参加调查,而在这8个州73%的大豆田使用草甘膦。

51. 2D NMR studies of Metal(Au,Pd) Complexes Containing 2-Mercaptopyridine-1-oxide Ligands and Chiral Phosphine Ligands

含手性膦配体和邻巯基氧化吡啶配体的金,钯配合物的2D NMR研究

52. Keywords diamine containing fluorine and phosphine oxide;copolyimide;adhesiveness;

含氟和氧膦二胺;共缩聚型聚酰亚胺;附着力;

53. Keywords Fe-only hydrogenase, H-Cluster, Diiron azadithiolate,Phosphine, Redox chemistry, Bioinorganic chemistry;

唯铁氢化酶;氢簇;双铁氮杂硫醇盐;膦配体;氧化还原;生物无机化学;

54. Keywords Fe-only hydrogenase;Diiron Complex;Phosphine ligand;Decarboxylation reaction;Internal base;

唯铁氢化酶;铁硫配合物;膦配体;脱羧反应;分子内碱基;

55. It also protects against carbon monoxide, smoke, hydrogen cyanide, sulfur dioxide, other gases, particulates, fumes, soot, ammonia, chlorine, phosphine, and radiant heat.

它还可以防止一氧化碳,烟雾,氰化氢,二氧化硫,其他气体,颗粒,烟雾,烟尘,氨,氯,磷,和辐射热的危害。

56. Influence of moisture content and loading degree of wheat on absorption rates to phosphine

小麦水分和装满度对磷化氢吸附率的影响

57. It was reviewed several popular studied problems of phosphine as a respiration poison to insects in biochemistry at home and abroad recently.

就近年来国内外对磷化氢作为昆虫呼吸毒剂的生化研究热点问题,如昆虫对磷化氢的吸收;

58. Importance of phosphine discovery for the phosphorus biogeochemistry circulation, eutrophication and the phosphorus elimination from domestic wastewater, is prospected.

并展望了磷化氢的发现对磷的生物地球化学循环、水体富营养和城市污水除磷的重要意义。

59. A near infrared spectrometry used for determining water content of tris-[1-(2-methyl)aziridinyl]phosphine oxide(MAPO) was investigated by means of standard addition method and multiple stoichiometry.

应用标准加入法及多种化学计量学方法研究了三-1-(2-甲基氮丙啶)氧化膦(MAPO)中水分含量的近红外光谱测定方法。

60. Keywords valeraldehyde;butene;hydroformylation;water - soluble rhodium - phosphine catalyst;

戊醛;丁烯;氢甲酰化;水溶性铑膦催化剂;

61. Test of Phosphine Re-Circulation Fumigation for Wheat Mass Sealed with Plastic Film in Warehouse

房式仓单面封薄膜下磷化氢环流熏蒸试验

62. Keywords Chirality;Asymmetry;Phosphine ligands;Imines;

手性;不对称;膦配体;亚胺;

63. Keywords Chiral phosphine ligand;Nitrogen donor;Asymmetric catalysis;Review;

手性膦配体;氮给体;不对称催化;综述;

64. Studies on Supported-Water-Soluble Phosphine Rhodium Complex Catalyst

担载型水溶性膦铑配合物催化剂研究

65. Keywords Supported liquid phase catalyst;EXAFS;Rhodium Phosphine catalyst;Olefin hydroformylation.;

担载液相催化剂;EXAFS;铑膦催化剂;烯烃醛化;

66. Bis 4-carboxyphenyl phenyl phosphine oxide (BCPPO) is a preferable flame retardant because of its excellent thermal stability, thermo-oxidative stability and resisting-hydrolyzation.

摘要双(对-羧苯基)苯基氧化膦(BCPPO)具有较高的热稳定性、氧化稳定性和耐水解性,是一种有很好发展前景的阻燃剂。

67. Phosphine (PH3) is a kind of extremely toxic, highly active, reductive gas, produced by the reduction of P biogeochemistry cycle, and has been proved to be trace gas existing stably in the atmosphere.

摘要磷化氢(PH3)是一种剧毒、十分活泼的还原性气体,是磷生物地球化学循环的还原产物,已被证实是大气中稳定存在的痕量气体。

68. The conversion of phosphate into phosphine was an important biological reaction with potential value in application.

摘要磷酸盐转化成磷化氢是一个具有重要潜在价值的生物反应。

69. Cocatalytic Effect of New Surface-Active Phosphine in Long-Chain Olefin Hydroformylation

新型表面活性膦在长链烯烃氢甲酰化反应中的助催化作用

70. The Phosphine Circumfluence Fumigation Insect-killing Experiment for Newly-built One-storey Grain Storage

新建平房仓磷化氢环流熏蒸杀虫试验

71. METHODS 3,4,5-trimethoxy-triphenyl benzylidene bromide phosphine salt,the important precursor of the phosphine Ylide,was synthesis from deoxidize,bromization and addition.

方法以3,4,5-三甲氧基苯甲醛为原料,经过还原、溴代、加成三步反应得到叶立德前体3,4,5-三甲氧基苄溴三苯基膦盐。

72. Application of Organic Phosphine Tanning Technology on Sheepskin Garment Leather

有机膦鞣制技术在绵羊服装革生产工艺中的应用

73. Study on the chiral phosphine ligands containing nitrogen donor and correspondingcatalytic enantioselective reactions were reviewed.

本文就近年来所出现的含氮给体的手性膦配体及其不对称催化反应的研究进展进行了较为详细的评述。

74. The toxicity of phosphine resistant strains of Rhyzopertha dominica and Sitophilus oryzae to three protectants (malathion,pirimiphos methal and deltamethrin) was determined.

本文报道了两种主要储粮害虫谷蠹和米象的抗磷化氢品系对马拉硫磷、虫螨磷和溴氰菊酯 3种储粮保护剂的毒力测定。

75. In this paper,the basic demands of recirculation fumigation of phosphine in Chin ese national grain storage depots are discussed,which include safety,phosphine c oncentration,disribution,gas tightness,running state and corrosion.

本文讨论了中央直属储备粮食仓库采用有中国特色的环流熏蒸中应达到的基本要求,从熏蒸过程的安全性、浓度分布要求、气密性要求、以及设备工况、防腐蚀等方面进行了阐述。

76. Relationships between phosphine content of samples and their microbial populations and enzyme activities

样品磷化氢含量与某些微生物群落及酶活的关系

77. Formation and Release of Phosphine in Lake Sediments Under Simulative Environmental Conditions

模拟环境条件下湖泊沉积物中磷化氢的行为

78. Determination of Purity of Triphenyl Phosphine by CGC

毛细管气相色谱法测定三苯基膦纯度

79. The gastightness measurement with pressure test is very important in phosphine fumigation.

气密性测定在磷化氢熏蒸中具有重要的意义。

80. Keywords Gas Chromatography;Trialkyl Phosphine Oxide;ICP AES;Radiolytic Products.;

气相色谱;三烷基氧化膦;等离子体光谱;辐解产物;

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